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Smith, Watson

"The Chemistry of Hat Manufacturing Lectures Delivered Before the Hat Manufacturers' Association"

This is chemical replacement, and on
such replacement depends our powers of building up not only colours, but
many other useful and ornamental chemical structures. You have all heard
the old-fashioned statement that "Nature abhors a vacuum." We had a very
practical example of this when in our first lecture on water I brought
an electric spark in contact with a mixture of free oxygen and hydrogen
in a glass bulb. These gases at once united, three volumes of them
condensing to two volumes, and these again to a minute particle of
liquid water. A vacuum was left in that delicate glass bulb whilst the
pressure of the atmosphere was crushing with a force of 15 lb. on the
square inch on the outside of the bulb, and thus a violent crash was the
result of Nature's abhorrence. There is such a kind of thing, though,
and of a more subtle sort, which we might term a chemical vacuum, and it
is the result of what we call chemical valency, which again might be
defined as the specific chemical appetite of each substance.
Let us now take the case of the production of an aniline colour, and let
us try to discover what aniline is, and how formed.


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