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Smith, Watson

"The Chemistry of Hat Manufacturing Lectures Delivered Before the Hat Manufacturers' Association"

The Peruvian borax sometimes
contains nitre. For testing the purity of refined borax the following
simple tests will usually suffice. A solution of the borax is made
containing 1 part of borax to 50 parts of water, and small portions of
the solution are tested as follows: _Heavy metals_ (_lead_, _copper_,
etc.).--On passing sulphuretted hydrogen into the solution, no
coloration or precipitate should be produced. _Calcium Salts._--The
solution should not give a precipitate with ammonium oxalate solution.
_Carbonates._--The solution should not effervesce on addition of nitric
or hydrochloric acid. _Chlorides._--No appreciable precipitate should
be produced on addition of silver nitrate solution and nitric acid.
_Sulphates._--No appreciable precipitate should be produced on adding
hydrochloric acid and barium chloride. _Iron._--50 c.c. of the solution
should not immediately be coloured blue by 0.5 c.c. of potassium
ferrocyanide solution.
_Soap._--Soap is a salt in the chemical sense, and this leads to a wider
definition of the term "salt" or "saline" compound.


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